Volibear & Braum Synergy
Volibear Top and Braum Support win 55.1% of 1,901 Low Elo games together, +1.8 points vs expected, 2-patch window 26.19-26.20.
Researched on LoL patch 26.20. Tips are written to hold at any rank; stats come from Low Elo ranked games up to patch 26.20.
Why this duo works
Braum's Concussive Blows rewards allies who can keep attacking after he starts a mark, and Volibear brings an attack-speed ramp plus a Q attack that sticks to a target. When Volibear starts a skirmish, Braum can add the first stack and Volibear's follow-up attacks help finish the stun, layering their crowd control.
Playing the duo
After Braum starts Concussive Blows(P) with an attack or Winter's Bite(Q), allied basic attacks add stacks; Volibear's passive grants him attack speed as he attacks and casts abilities, helping him apply those follow-up hits quickly.
How to play as Volibear
When Braum tags a target with an attack or Winter's Bite(Q), use Thundering Smash(Q) to reach it and keep attacking; your follow-up hits help finish Braum's passive stun.
How to play as Braum
Use Winter's Bite(Q) on the target Volibear is approaching, then stay in range while he attacks to finish Concussive Blows(P); if your Q misses, wait until one of your attacks starts the stacks.
Sources
These notes come from r/BraumMains, checked against the champions' abilities.