Volibear vs Zac Jungle Matchup
Volibear Jungle wins 52.4% of 397 Low Elo games against Zac Jungle, +0.6 points vs expected, 2-patch window 26.19-26.20.
Researched on LoL patch 26.20. Tips are written to hold at any rank; stats come from Low Elo ranked games up to patch 26.20.
How to play as Volibear
If Zac starts channeling Elastic Slingshot(E) while you are already in Thundering Smash(Q) reach, stun him before he releases to cancel the charge and prevent the knock-up.
Pressure Zac early with a three-camp gank or invade when your lanes can move, then turn the pressure into objectives. Don't spend extra time chasing him for bloblets if his team can collapse.
Elastic Slingshot(E)'s charge is interrupted by immobilizing effects, and Thundering Smash(Q) stuns. If Volibear reaches Zac before he releases E, Q can stop the launch.
How to play as Zac
Keep Elastic Slingshot(E) available during your early clear if Volibear may invade; a Zac player recommends holding E so you can escape before the duel turns into a kill.
When Cell Division(P) triggers, Zac splits into four attackable bloblets and revives if any bloblets remain when they recombine.
Sources
These notes come from LoL Wiki, leagueoflegends.com, r/Jungle_Mains, and r/VolibearMains, checked against the champions' abilities.